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UN identification number

UN3136: Trifluoromethane, refrigerated liquid

UN3136 appears 1 time in the Hazardous Materials Table (49 CFR §172.101). Hazard class 2.2.

ID numberUN3136
Hazard class2.2
Packing groupnot assigned
Label codes2.2

All §172.101 entries for UN3136

Proper shipping nameClassPGLabels
Trifluoromethane, refrigerated liquid2.2—2.2

Open any entry for packaging sections, special provisions, air limits and vessel stowage.

What it means

2.2
Class 2.2 — Non-flammable, non-poisonous gas. Compressed gases that aren't flammable or toxic but can still be dangerous under pressure — for example nitrogen and compressed air.

Label codes (column 6): 2.2 → Non-flammable gas label.

UN numbers are recognized for international and domestic transport.

Example basic description

UN3136, Trifluoromethane, refrigerated liquid, 2.2

Proper shipping name shown without the table's italic descriptive text. Order per §172.202: ID number, proper shipping name, hazard class, packing group. Example only — add technical names, “RQ”, quantities and other elements your shipment requires.

What to check next

  1. Match the name. Compare your SDS Section 14 to the proper shipping names above and pick the row with your packing group.
  2. Read the special provisions on the entry page (§172.102) — they can add limits or exceptions.
  3. Check packaging — the entry page lists the Part 173 sections for exceptions, non-bulk and bulk.
  4. Labels & placards. Placarding depends on class and quantity — see Table 1 vs Table 2.
  5. Emergency response. Find the response guide for UN3136 in the current PHMSA Emergency Response Guidebook.
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Common questions about UN3136

What is UN3136?

UN3136 is the identification number for Trifluoromethane, refrigerated liquid in the DOT Hazardous Materials Table (49 CFR §172.101).

What hazard class is UN3136?

UN3136 is listed under hazard class 2.2 (non-flammable, non-poisonous gas).

What packing group is UN3136?

Packing group for UN3136: not assigned. Where several rows exist, the packing group that fits your material decides which row applies.

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Source: Hazardous Materials Table (49 CFR §172.101), eCFR.gov — current as of Oct 23, 2026. View the official table. Reference only — verify current requirements before shipping.