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UN identification number

UN1339: Phosphorus heptasulfide

As listed: Phosphorus heptasulfide, free from yellow or white phosphorus

UN1339 appears 1 time in the Hazardous Materials Table (49 CFR §172.101). Hazard class 4.1, packing group II.

ID numberUN1339
Hazard class4.1
Packing groupII
Label codes4.1

All §172.101 entries for UN1339

Proper shipping nameClassPGLabels
Phosphorus heptasulfide, free from yellow or white phosphorus4.1II4.1

Open any entry for packaging sections, special provisions, air limits and vessel stowage.

What it means

4.1
Class 4.1 — Flammable solid. Solids that ignite readily or can cause fire through friction, plus self-reactive and desensitized explosive materials.

Packing group ranks danger within the class: PG II = medium danger.

Label codes (column 6): 4.1 → Flammable solid label.

UN numbers are recognized for international and domestic transport.

Example basic description

UN1339, Phosphorus heptasulfide, 4.1, PG II

Proper shipping name shown without the table's italic descriptive text. Order per §172.202: ID number, proper shipping name, hazard class, packing group. Example only — add technical names, “RQ”, quantities and other elements your shipment requires.

What to check next

  1. Match the name. Compare your SDS Section 14 to the proper shipping names above and pick the row with your packing group.
  2. Read the special provisions on the entry page (§172.102) — they can add limits or exceptions.
  3. Check packaging — the entry page lists the Part 173 sections for exceptions, non-bulk and bulk.
  4. Labels & placards. Placarding depends on class and quantity — see Table 1 vs Table 2.
  5. Emergency response. Find the response guide for UN1339 in the current PHMSA Emergency Response Guidebook.
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Common questions about UN1339

What is UN1339?

UN1339 is the identification number for Phosphorus heptasulfide in the DOT Hazardous Materials Table (49 CFR §172.101).

What hazard class is UN1339?

UN1339 is listed under hazard class 4.1 (flammable solid).

What packing group is UN1339?

Packing group for UN1339: II. Where several rows exist, the packing group that fits your material decides which row applies.

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Source: Hazardous Materials Table (49 CFR §172.101), eCFR.gov — current as of Oct 23, 2026. View the official table. Reference only — verify current requirements before shipping.