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UN identification number

UN0219: Trinitroresorcinol or Styphnic acid

As listed: Trinitroresorcinol or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass

UN0219 appears 1 time in the Hazardous Materials Table (49 CFR §172.101). Hazard class 1.1D.

ID numberUN0219
Hazard class1.1D
Packing groupnot assigned
Label codes1.1D

All §172.101 entries for UN0219

Open any entry for packaging sections, special provisions, air limits and vessel stowage.

What it means

1.1D
Class 1.1D — Explosives. Materials that can explode, burst, or rapidly release energy. Divisions 1.1–1.6 rank the type of hazard, from mass explosion (1.1) to extremely insensitive articles (1.6).

Label codes (column 6): 1.1D → Explosive 1.1D label.

UN numbers are recognized for international and domestic transport.

Example basic description

UN0219, Trinitroresorcinol or Styphnic acid, 1.1D

Proper shipping name shown without the table's italic descriptive text. Order per §172.202: ID number, proper shipping name, hazard class, packing group. Example only — add technical names, “RQ”, quantities and other elements your shipment requires.

What to check next

  1. Match the name. Compare your SDS Section 14 to the proper shipping names above and pick the row with your packing group.
  2. Read the special provisions on the entry page (§172.102) — they can add limits or exceptions.
  3. Check packaging — the entry page lists the Part 173 sections for exceptions, non-bulk and bulk.
  4. Labels & placards. Placarding depends on class and quantity — see Table 1 vs Table 2.
  5. Emergency response. Find the response guide for UN0219 in the current PHMSA Emergency Response Guidebook.
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Common questions about UN0219

What is UN0219?

UN0219 is the identification number for Trinitroresorcinol or Styphnic acid in the DOT Hazardous Materials Table (49 CFR §172.101).

What hazard class is UN0219?

UN0219 is listed under hazard class 1.1D (explosives).

What packing group is UN0219?

Packing group for UN0219: not assigned. Where several rows exist, the packing group that fits your material decides which row applies.

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Source: Hazardous Materials Table (49 CFR §172.101), eCFR.gov — current as of Oct 23, 2026. View the official table. Reference only — verify current requirements before shipping.